Chap 19 & 20 Practice Problems

Chap 19 & 20 Practice Problems - Pr actice Pr oble ms f...

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1. Draw structures corresponding to the following IUPAC names: a) 2,3-Dimethylhexanoic acid b) 4-Methylpentanoic acid c) trans -1,2-Cyclobutanedicarboxylic acid d) o-Hydroxybenzoic acid 2. Rank the following compounds in order of increasing acidity. a) Benzoic acid, p -methylbenzoic acid, p -chlorobenzoic acid b) p -nitrobenzoic acid, acetic acid, benzoic acid 3. Draw structures corresponding to the following IUPAC names a) cis -1,2-Cyclohexanedicarboxylic acid b) Heptanedioic acid c) 2-Hexen-4-ynoic acid d) 4-Ethyl-2-propyloctanoic acid 4. Using 13 CO 2 as your only source of labeled carbon, along with any other compounds needed, how would you synthesize the following compounds? (You may have to use reactions from previous chapters.) a) CH 3 CH 2 13 COOH b) CH 3 13 CH 2 COOH Practice Problems for Chapter 19-20
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5. The following synthetic schemes all have at least one flaw in them. What is wrong with each? a)
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Chap 19 & 20 Practice Problems - Pr actice Pr oble ms f...

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