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chm2210ps6sol - Organic Chemistry I Problem Set 6 Answer...

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CH 3 CH 2 CH CH CH 3 CH 3 CH CH 3 CH 3 Cl H Cl H CH 3 H H CH 3 CH 2 CH CH 2 CH 3 CH 3 C C CH 3 CH 3 CH 3 H CH 3 Cl Cl H H CH 3 CH 2 CH 3 CH 2 Organic Chemistry I Problem Set 6 Answer Key Alkanes and Conformation I. Write names (IUPAC or common) for the following structures: 1. 2. 3-ethyl-2,4-dimethylpentane cis -1,3-dichlorocyclopentane 3. 4. cis -1,2-dimethylcyclohexane cyclopropylcyclopentane 5. 6. bicyclo[3.1.0]hexane 1,2-dicyclohexylbutane 7. 8. 2,3-dimethyl-2-butene 1-isopropyl-3-methylcyclopentane 9. 10. trans -1,2-dichloropropene 2-ethyl-1-butene
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CH 3 C CH 3 CH 3 CH 3 CH 2 CH CH 3 CH 3 Br CH CH 2 CH 2 CH 2 H 2 C CH CH 2 CH 3 CH 3 CH 3 CH 3 H H H CH 3 H CH 3 CH 3 H H CH 3 CH 3 CH 3 H CH 3 H H II. Write structural formulas: 1. neopentane 2. isobutyl bromide 3. sec -butylcyclopentane 4. trans -1,2-dichlorocyclopropane III. Answer these: 1. Construct an energy diagram for rotation about the C 2 – C 3 bond axis of 2- methylbutane. Write Newman projections at all maxima and minima.
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