chm2210ps19sol

chm2210ps19sol - products: 10. 11. 12. 13. 14. adjacent Brs...

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CH 3 -CH=CH 2 KMnO 4 / H 3 O+ heat CH 3 CH 3 H 2 Pt CH 2 C CH 3 CH 3 1. O 3 2. Zn / H 2 O / H + cis-2-butene CH 2 I 2 Zn(Cu) OH CH 3 H 2 SO 4 heat major product CH 3 -CH 2 -CH 2 -Cl KOH (alc) heat 1. (BH 3 ) 2 2. H 2 O 2 / OH - C CH 3 OH O + CO 2 CH 3 CH 3 Br H H OH Organic Chemistry I Problem Set 19 Answer Key Alkene Reactions I. Write structural formulas for the products and show stereochemistry when necessary. 1. 2. 3. 4. 5. 6. 7. 8. 9. Br 2 / H 2 O KMnO 4 / OH - / H 2 O cool H H HO OH CH 3 C CH 3 O O H H + CH 2 C CH 3 CH 3 Cl 2 / CH 3 OH CH 2 C CH 3 OH CH 3 Cl CH 3 CH 2 CH CH 3 CH 2 CH 2 CH 3 OH
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1. O 3 2. Zn / H 2 O / H + C 8 H 14 CH 3 C CH 2 CH 2 CH 2 CH 2 C CH 3 O O C 9 H 16 O 3 Zn/H 2 O/H+ CH 3 C CH 3 O 2 + CH CH 2 HC O O CH CH 2 HC O O II. For the following, write the structures for the molecular formulas given for reactants and
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Unformatted text preview: products: 10. 11. 12. 13. 14. adjacent Brs trans ////////////////// ////////////////////// C 6 H 12 1. O 3 2. Zn / H 2 O / H + CH 3 C CH 3 O 1. O 3 2. Zn / H 2 O / H + C 8 H 12 CH CH HC O O CH 3 CH CH HC O O CH 3 C 6 H 8 Br 2 C 6 H 8 Br 4 excess H 2 Pt KMnO 4 cold KMnO 4 hot, H + C 6 H 12 C 6 H 12 O 4 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 Br Br Br Br OH OH HO HO OH OH HO HO +...
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This note was uploaded on 02/23/2010 for the course CHEM 201 taught by Professor Smith during the Spring '10 term at Duke.

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chm2210ps19sol - products: 10. 11. 12. 13. 14. adjacent Brs...

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