Appendices

Appendices - ee: Appendices 1A 1B 1C NMR: Proton Chemical...

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Appendices e 1A NMR: Proton Chemical SHifts 1244 ± B ±MR: SpI²-SpIn CoupLI²g Constants 1246 1 C ±MR: 13 C ChEmIcal ShIfts in OrganIc Compounds ±247 2a ³R: CharacterIstIc ³²frared G´µup F´equEncIes ±248 2B ³R: Cha´acte´IstIc ³nfrared Abso´ptIons of FunctIonaL Groups 1251 3 UV: The Woodwa´d¶FIese´ RuLes for P´EdIctIng UV-VIsIbLe Spect´a ±253 4A Methods a²d Suggestio²s fo´ Proposi²g Mecha²Isms ±257 ²B SuggEstIo²s for Developing MuLtistep Syntheses 1260 5 pK· Values for RepresentatIve Compounds 1261 1243
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1244 Appendices APPENDIX 1A NMR: Proton Chemical ShIfts Structural Type o Value and range" 14 13 12 11 10 9 8 7 6 -' ± 4 3 O TMS, O.OOO ±±±. ±±±± ±±±± ±²±² ²³±² ±±±± ±±±± ±±±± ±³±± ±±±± ±±±± ±±±± .²±² ²±²± ±±±. .±±± ±±³± ±±´² ²²±± ³±±³ ±±±± ±±±± ±±±± ±±±± ±±±± ±±±. ±±±± ±±µ± ±³ . -CH2 - ¶ cyclopropane .. ±± .... . ... . ... . ... . ... . .±. ²±³± ±³±± . .³. . ... . ... . ... . ... . ... . ... . ... . ... . ... . ... . ... . ... . ... . .´. . ... . ³³±³ ± +± CH4 ²³´´ ´ ´´ µ¶². .. ²±± ±.±± ±.±± ±±±. .... .... ..±. . ± .. ±. µ..² ´ .². .... ².±± ±. .±±± ±±±± .±.± ..±± .±±. . . .±. . .... ±... . ...± . ±· ±±.±. .... ... µ µ´. . ´.¸´ .´ ¹´´.² . R·H¶ monome¸¶ ve¸y dilute solUtIon ±± ±±³± ²±±± ±±±± ±±±± ±±±± ±±±± ±±±± ±±±± ±±±± ±±±± ±±±± ±±±± ±±¹² ²±²º²³²² ²±²² ²±²± ³±±³ ±±²± ±±»± ²±²± ²±²¹ ²±² ³ I CH3¼C¼(½atU¸ateD) ²²´´ ¹ . ±²²². . ±²± .±²± .±.² ±.±. .².± ¾ .±. ².²² . ..² . ... ´µ. . µ³. . ..´. µ... ´.´´ .²²´ ´²²´ . .´´. ...² ´.². ².². ±. . .´²´² ´.´² ´²´µ .²´² .±.± . :±² ³´³´ . i R2NH b , 0.1-0.9 mole f¸actIon In an ¿ne¸t solvent ..... ²´². ...² ². ..². .µ. . ..². ±. . ´.² ..²´ .´²² . ... .... .. µ. ±. µ ..... . ².. .. ´² . . .. j . ± C ² ²³´µ I i I I I CH3¼ r ¼ r ¼X (X = CÀ, B¸Á I, ·H, ·R, C=·, N) ´¶. . ..µ² . ± . .... µ. .² .´µ´ .´´´ ´µ´´ .. .... .±.± .±.± . ..² .... . ±.± .. ; ¶·¶ ··¶ . ÂCH2-(satU¸ateD) ±² ²±²± ±±±± ±±±± .±±± ±±±² ±±²± ²±Ã² ±±±± ±±Ã± ¾±±± ±±±± ±±±± ±±±± ±±±± ±±±± ±±±± ±±±± ±±±± ±±±± ±¾.± ±±±± ±±±± ±±±± .±±± ±±±± ±±±± ±±±. ±±±± ±±±± ±±±± ±Ä± .±±± ±±± ± RSH Å ±.±. ².± ¾ . ±.²± ². ...± ±. .. ..±. . ´... ¹´.µ ´.µ² ².±± ±² ± ´ ... . .... ±±. . .... ..¸. ...± . ... ±. ±±±± .±±± . .±.± ¸¸¸¸ ¸¸¸ . RNH2 b Æ 0.1±0²9 mole fÇactIon In an Ine¸t solvent± .³. . ...´ ´´. . ±... . ±±. . ±±± . .±± ..± . ±.±. ±.±. . . ²± . ¹º» ¼¼½¼ ½½¼ ± I ¼ T 'ÈUrÉt : Ê ²± ±± . ± ±²±± ² . ± ¾ . ¾ ±±± ±±.± .±.± .±±± ±±.± . . ..±± . ±±±. . . ±±.± .±.± ±±.± ±.±. ±.±. ±.±. ··¸· r ±.±² .±± ± CH3 R X (X - CÀ¶ B¸, I, ·H, ·R, ·A¸, N ¾ ±. ..´. . ...² . . . .±±± ±±±. ±... .. ±± ±.±± ±±±± ±.±± ±±±± ±.±. .²±. ±. .² ².±. .²±² ¾¿ ÀÀÀÀ ÀÀÀ ± CH3 Ë / / CÌC Í ´³´´ µ´. . .²´ . ± ± .
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Appendices - ee: Appendices 1A 1B 1C NMR: Proton Chemical...

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