Solutions_Manual_for_Organic_Chemistry_6th_Ed 30

Solutions_Manual_for - 1-40 continued(c:0:0 II II C H3 C C CH3 minor H 0.1-1 C H3 C = C C CH3 I:0 major H I II:0.1-1 C H3 C C = C CH3 II:0 n

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1-40 continued (c) :0 ± ±0 : .. - ±0: :0: .. ² :0: :0: ² . ³ ±± CH3³C´ ? µCµCH¶ ± ±± ± .±²³´ 1-µ¶ ·¸ CH3 ´ C = C · C ´ CH3 .±² ¸ 1-µ¶¹¸ CH3 ¹ C µ C º C ´Ch3 I i H minor H » \ Major MaJor } - ¼¼¼¼ ± ² ¼¼ ¼ _/ Y NegaTive charge on eleCtRoNegaT´ve atoµs¶eqUal eNergy ·d) + c½¶¾C´C¿cÀNÁ0  ± ± ± ± •• ³ ² ± + CH¶ÃC¿CµCÄNÅ0  CH3¾CÆCÇcÈNÉÊ ± ´ i ± ± ³ I ± ± ± ³³ H H H :0: minor H H H :Ê ± H H H ±0 ± ¸Nor ¹aºor»negat´ve CHaRge oN eLectrone gat´ ve aToMs NOTE: The two structures below ar± resonanc± foRs, va²ing From th± first ³wo structures in part (d) by the dI´erent positions of the double bonds in th± N02. UsuaLly, chemists omit draWing th± s±cond ForM oF the Nµ¶ group aLthough w± all und±rstand that its pr±s±nc± is impli±d· ¸t is good id±a to dra¹ all the
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This note was uploaded on 02/27/2010 for the course CHEM 140 taught by Professor Wade during the Spring '10 term at Whitman.

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