Solutions_Manual_for_Organic_Chemistry_6th_Ed 31

Solutions_Manual_for_Organic_Chemistry_6th_Ed 31 - 1 -4 1...

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1-41 continued (c) H±C²CH3 \ H h³C´C ± N: \ H ² H³C=µ¶N: \ h no resonance stabilization more staBle-resonanCe sTaBiLized ·e) more stable¸Resonance staBiLized CH3±¹ º ³CH3 CH3»C»Ch3 + ³´µ.± I-¶ · ¸ CH3 ´ ¼CH3 CH3»C»C½3 + C ¾ . µH 2 \ ' H C C ¿À ' H ± H no resonance stabiLIzation h Á Ch3´CÂCh3 I CH3ÂCÂCh3 + moRe stabLeÃresonanÄe stabilized no resonanÄe stabIÅIzation ÆÇ4È TÉese pK A values froM tÉe text, Table 1-5Ê and Ëppendix 5 provide tÉe answersÌ ÍÉe LoweR tÎe pK A Ï tÐe stronger tÉe acidÑ Least acidic ÒoSÓ acidIc ¹H3 ÔÔ < < < 1Ç4Ô Conjugate bases of tÉe weakest aciDs wilL be tÉe strongest basesÌ TÉe pÕ A VaLues of tÉe conjugate acids are Listed ÉereÖ ·TÉe reLative oRder of tÉe first two was dete×ined froM tÉe pK
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This note was uploaded on 02/27/2010 for the course CHEM 140 taught by Professor Wade during the Spring '10 term at Whitman.

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