Solutions_Manual_for_Organic_Chemistry_6th_Ed 35

Solutions_Manual_for_Organic_Chemistry_6th_Ed 35 - CHAPTER...

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Unformatted text preview: CHAPTER 2-STRUcTURE AND PrOPERTIES oF oRGAnic MoLECuLES 2- 1 The fundamental principLe of organic chemistry is that a molecuLe's chemIcaL And pHysical properties depend on tHe moLecuLes stRuctUre: the structurefunction or structurereactivitY correlation. t is essential tat you understand the tHreedimensional nature of organic moLecuLes, And theRe s no better device to assis o han a MOECar MODE sE O aE sOnG EnCOaGE O sE ODEs rEGuaL whEn EanG the text and workng the probLems (a) requires se of ModeLs (b) , f The wedge bonds represent bonds Coming out of the plane of the paper toward you " / / . The ashed bonds represent bonds going behind the plane of the paper J \ J\. 22 (a) The hbridizatioN of oxygen is sp 3 since it has two sigMa bons and wo pAis of non bonding eectons The reason that the bond angLe of 1 045 is Less than the perFeCt tetrahedal ange oF 1 095 is that the Lone pairs in...
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