Solutions_Manual_for_Organic_Chemistry_6th_Ed 46

Solutions_Manual_for_Organic_Chemistry_6th_Ed 46 - 2 2...

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2-24 continued (g) aldehyde: contains a carbonyl group with a hydrogen on one side H H a I I iI H-C-C-C±H I ± ² ² ³) ester´ contains a carbonYl group with an OµC on one side H A ² ² 1/ I H±C±C±O-C±H ± I H H (h) aromatic hydrocarbon¶ a cyclic hYdrocarbon with alteRating double and single bonds o ·k) amine¶ contaIns a nitrogen bonded to one, two, or three carbons H ² or R group ± I H ±¸¹ N º H or R group ± ² (m) nitrile» contains the carbon¼nitrogen tr½ple bond¶ ² 3 ¸ - ¸ N ·i) ca¾boxyLic acid¿ contains a carboNYL g¾oup with an OH group on one side ² 0 ³ II ²ÀCÁCÀOÂH ³ H ·Ã) amide¶ contains a carbonyl group with a nit¾ogen on one side ² a ² ³ II ´ H-¸Ä¸-ÅºÆ i Æ 2±25 Models show that the tetrahedral geoÇetry of C²
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Unformatted text preview: 2 2 precludes stereoisomers. 2-26 (a) H " / C H C _ \ H / \ H (b) yclopropane must have 0 bond angles comPaed with te usual sp 3 bond angle of 109 . in an acYclic olecule (c) ike a bent sping, bonds that deviate from their noal angles or positions are highly stained Yclopropane is reactive because breaKing the ng relieves the strain. 2-27 (a) f + 0 " " \ " H H H (d) H ' / H behind the plane of The paper ) / J ' C H H j ' H a sp , al = 109 (b) 0_ ? Sp 3 , no bond angle because oXYgen is bonded to onlY one ato (c) ( ", N-N H I H both sp 3 all = 109 angles around sp 3 atoms 09 angles arouNd sp carbon 120 36...
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This note was uploaded on 02/27/2010 for the course CHEM 140 taught by Professor Wade during the Spring '10 term at Whitman.

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