Solutions_Manual_for_Organic_Chemistry_6th_Ed 51

Solutions_Manual_for_Organic_Chemistry_6th_Ed 51 - 2-38...

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Unformatted text preview: 2-38 Diethyl ether and I -butAnol each HAve one oxygen, so each can form hydrogen bonds wTh wATer (waTer supples THe H for hydrogen bondNg wTh dethyl eTHer); ther watEr soluBlTEs should be sMilar. he bolng ponT of I buTanol s much Hgher ecause ThesE Molecules can hydrogEN bond wTh each oTher Thus requrng MorE enErgy To sEparaTe onE olEcUlE fro anoThEr Ethyl ETEr MolEcUlEs cannoT hydrogen bond wTh Each oThEr so T s relaTively easy To sEparaTE theM CC -0 CC CCC O deThyl eTher cAn hydrogen boNd wth waTer cannot hydrogen bond wiTh itSelF 39 C ] eth y I pyRo d NE b.p 8 1 pperdine bp 06 I -buTaNol can hydrogEn bond wTh WaTer cAn hydrogen bond wTh i Tself teTrahydropyran Bp 88 o cyc!openTanol BP 14 1 C (a) ipeidine hAs an N-H bond so iT can hydogen bond with othEr olecules of TsElf -ethylpyrroldne has no...
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