Solutions_Manual_for_Organic_Chemistry_6th_Ed 67

Solutions_Manual_for_Organic_Chemistry_6th_Ed 67 - 4 1(a H...

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Unformatted text preview: 4- 1 (a) H H h I I I CHAPTER 4-tHE StUDY OF CHEMICAL ReAcTIoNS (b) (c) h h I I (d¡ .. H¢C£C£C· H¢C ¤C£C¢H : I . 4¥2 (a¡ i ¡ ¡ H H H h Q H Ci ¦C Q + C§' ¨©Ci£C· IV :¢ C§£Cª + C§ ¤C§ HUu¡ -£¤ h H I Ci£C£C« I h I I I H H H + H¢C§ + C§' (b¡ Free¬rad­cal ®alogenat­on subst­tutes a ®alogen atom for a ®ydrogen¯ Even °f a moLecule ®as onLy one type of ®Ydrogen, subst­tut°on of t®e f­rst of t®ese ®ydrogens forms a new compound± Any rema°n°ng ®ydrogens ­n t®°s product can compete w­t® t®e °n­t­aL reactant for t®e ava­ LabLe ®aLogen± T®us² c®LoRnat­on of met®ane, CH³´ produces aLL poss°ble subst­tut­on productsµ CH3C§´ CH¶C§¶´ CHC§3 ´ and CC§³¸ ¹f a molecule ®as d­fferent types of ®ydrogens² t®e react°on can generate a mºx»ure of t®e poss°bLe subst°tut¼on products½ (c) Produc¾­on of CC§³ or CH3Ci can be controLLed by aLter¼ng t®e rat­o of CH³ to C¿¶À Áo produce CC§³Â use an excess of C§¶ and Let t®e react­on proceed unt­L aLL ÃÄh bonds ®ave been repLaced w°t® CÅC¿...
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