Solutions_Manual_for_Organic_Chemistry_6th_Ed 67

Solutions_Manual_for_Organic_Chemistry_6th_Ed 67 - 4- 1 (a)...

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Unformatted text preview: 4- 1 (a) H H h I I I CHAPTER 4-tHE StUDY OF CHEMICAL ReAcTIoNS (b) (c) h h I I (d .. HCCC HC CCH : I . 42 (a i H H H h Q H Ci C Q + C' CiC IV : CC + C C HUu - h H I CiCC I h I I I H H H + HC + C' (b Freeradcal alogenaton substtutes a alogen atom for a ydrogen Even f a moLecule as onLy one type of Ydrogen, substtuton of te frst of tese ydrogens forms a new compound Any remanng ydrogens n ts product can compete wt te ntaL reactant for te ava LabLe aLogen Tus cLoRnaton of metane, CH produces aLL possble substtuton products CH3C CHC CHC3 and CC f a molecule as dfferent types of ydrogens te reacton can generate a mxure of te possbLe substtuton products (c) Producon of CC or CH3Ci can be controLLed by aLterng te rato of CH to C o produce CC use an excess of C and Let te reacton proceed untL aLL h bonds ave been repLaced wt CC...
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