Solutions_Manual_for_Organic_Chemistry_6th_Ed 71

Solutions_Manual_for_Organic_Chemistry_6th_Ed 71 - 4- 1 6 (...

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4-16 (a) t numbers are kJ/mole + 192 reaction coordinate - (b) The step Leading to the highest energy ±rAnsition state is rate²LimIting. ³n tHis MecHanisM, t´e first propagation step is rateµlimiting: Br· + CH4 ± ¶BR + CH3 (c) ( 1 ) [T-±²³´±µ ; 1 + "8·" means partia¸ radical characteR on tHe atom ) (2) [h- tT'±±±H²±³±±±´; r µ H / 8 . 8 . ] + ¹3º H - ±²²²³´²´ Br » ¼ »»½»Br (d) WO for the reaction is the sum of the wo values of the individual ProPagation stePs (RefeR to ¾He solution to 4µ10 (a) and (b¿À 4Á17 initiation ¹1º + 67 kJ/mole + ² 101 kJ/Mole = ² 34 kJ/mole
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