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Solutions_Manual_for_Organic_Chemistry_6th_Ed 77

Solutions_Manual_for_Organic_Chemistry_6th_Ed 77 - 4-3 1...

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4-3 1 :O:H II (I II - .. H C-C-C-C-CH3 + :O-H 3 I H base :0 : :0: II II -- H20 + .. - :0: :0: .. - :0: :0: I I I II I / C .. .. - / C .. .. H C .... . ' c 'CH __ _ ", C , ", C __ __ C / C H C .. .. . ' C .... . 'CH H C / 'C / 'CH 3 I 3 H 3 I 3 3 I 3 H H -- H-Base + 4-34 Please refer to solution 1 -20, page 1 2 of this Solutions Manual. 4-35 transition states (a) and (c) /� (b) Mio is negative (decreases), so the reaction is exothermic. t 4-36
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