Solutions_Manual_for_Organic_Chemistry_6th_Ed 99

Solutions_Manual_for_Organic_Chemistry_6th_Ed 99 - 5 -26...

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Unformatted text preview: 5 -26 continued (i) B r CI C c hiral molecule, but no chiral centers ( " C=C=C' � " Br (j ) (Y I * chiral "- s Br ( k) oa chiral (m) Bf plane of symmetry ( I) p l ane of symmetry meso; achiral C n) ( 0) chiral R R s ( NH2 i s group 1 , C H3 i s group 4) chiral c hiral 5 -27 (a) <;: H3 *= c hiral H - C - CI c::====�> e n anti orner <;: H3 CI - C - H C H2CH3 *= en anti orner > C H2CH3 n o plane of symmetry no diastereomer chiral structure c hiral structure n o plane of symmetry no diastereomer chiral structure chiral structure <;: H3 = H - C - Br * ( c) Br - C - H Br - C - H CH2CH2CH3 *- *I en anti orner > H - C - Br CH2CHzCH3 c hiral structure * I H - C - Br Br - C - H CH2CH2CH3 * * I - n o plane of symmetry c hiral structure chiral structure c::====�> ( inverting two groups on the diastereomer b ottom asymmetric c arbon i nstead of the top one would also gi ve a diastereomer) 92 ...
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This note was uploaded on 02/27/2010 for the course CHEM 140 taught by Professor Wade during the Spring '10 term at Whitman.

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