Solutions_Manual_for_Organic_Chemistry_6th_Ed 106

Solutions_Manual_for_Organic_Chemistry_6th_Ed 106 - CHAPTER...

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Unformatted text preview: CHAPTER 6-ALKYL HALIDES: NUCLEOPHILIC SUBSTITUTION AND ELIMINATION 6-1 (a) vinyl halide (b) alkyl halide 6-2 (a) In problems like part (a), draw out the whole structure to detect double bonds. J-C-I (f) � ,, H H (c) aryl halide (d) alkyl halide (b) Br Br B r -C- Br ,, (g) Br 6-3 IUPAC name; common name; degree of halogen-bearing carbon l-chloro-2-methylpropane; isobutyl chloride; 1° diiodomethane; methylene iodide; methyl 1,I-dichloroethane; no common name; 1° 2-bromo-l,1,l-trichloroethane; no common name; all 1° trichloromethane; chloroform; methyl (f) 2-bromo-2-methylpropane; t-butyl bromide; 3° (g) 2-bromobutane; sec-butyl bromide; 2° (h) l-chloro-2-methylbutane; no common name; 1° (i) cis-l-bromo-2-chlorocyclobutane; no common name; both 2° U) 3-bromo-4-methylhexane; no common name; 2° (k) 4-fluoro-l,1-dimethylcyclohexane; no common name; 2° (I) trans-l,3-dichlorocyclopentane; no common name; all 2° (a) (b) (c) (d) (e) 6-4 Cl � I-C-H ,, ~ FX '-rH2F + (Cl (d) (e) vinyl halide (f) aryl halide I (e) Br Br H ( hl Cl or (CH3hCCI CI Cl Cl CI CI Cl > 0 Kepone® Cl ...
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