Solutions_Manual_for_Organic_Chemistry_6th_Ed 154

Solutions_Manual_for_Organic_Chemistry_6th_Ed 154 - 7 -26...

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7-26 (a) f.G o = tJ0 - Tf. So = + 116,000 IlmOL ± 298 K (i²7 ³·MOL) = ± ´1µ10¶ ¸¹ºO» = ± ´²¼½ k¾/ºO¿ (+19.3 kcAVÀOÁe f.G o Ãs pOsÃtÃvEÄ thE rEaCtÃOn Ãs disfavored Åt 25°Æ Çb) f.G ÈÉ Ê = ± 116Ķ0¶ ¸lÀOË Ì Í273 Î (ÍÏ7 ÐÑηºOÒ) = - 32Ó9Ô0 IlºOÒ = - 32Õ9 ÖÐ×ØÙ I ( ± 8ÚÔ ÖCaLÛÀOLE) f.G Ãs nEgatÃvEÄ thE rEaCtÃOn Ãs favoRed Åt ÍÔÔÔ°Æ 7Ü27 (Å) BasÃC and nuCÒEOphÃLÃC ºEChÅnÃsm: Ýa(ÞH}z Ãs Å strOng BasE (b) aCÃdÃC and EßECtrOphàßÃC ºEChanÃsºá thE cÅtaÒyst âs H+ (C) FrEE radÃCaß ChÅÃn rEãCtÃOnä thE CÅtÅÒyst Ãs a pErOxÃdE that ÃnÃtÃatEs FREE radÃCÅL rEÅctÃOns
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This note was uploaded on 02/27/2010 for the course CHEM 140 taught by Professor Wade during the Spring '10 term at Whitman.

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