Solutions_Manual_for_Organic_Chemistry_6th_Ed 159

Solutions_Manual_for_Organic_Chemistry_6th_Ed 159 - 7 - 3 8...

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Unformatted text preview: 7 - 3 8 continued (d) 7-39 Only (a), (b) and (d). ( a) major HH CH3-C-C-CH3 H OH I I I I mmor major alkene i somers are shown. Minor alkene i somers would also be produced in parts HH I I CH3-C=C-CH3 ( b) Br NaOC(CH3h - ( c) ( d) (a) 7 -40 II II CH3 CH3 II II CH3-C-C-CH3 HH CH3-C-C-CH3 Br Br h indered base + Zn .. ---....,� HH CH3COOH CH3-C=C-CH3 I I E+Z tl en H E+Z + H20 HOC(CH3h + ZnBr2 + NaBr + NaOH, ( b) (c) Q' 0 OR CH3COOH Q'0H H2S04, '" � H Br Br N aI, acetone Z n, .. Br tl .. Br KOC(CH3h .. .. ( d) Br ' h v 2 Q' (b) Br 0 0 0 KOC(CH3h .. 7 -41 (a) � o nly product + �+ J \ �---�,,�---� major 0 1\ minor 152 ...
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This note was uploaded on 02/27/2010 for the course CHEM 140 taught by Professor Wade during the Spring '10 term at Whitman.

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