Solutions_Manual_for_Organic_Chemistry_6th_Ed 170

Solutions_Manual_for_Organic_Chemistry_6th_Ed 170 - 8-12 I...

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8-12 Instead of borane attacking the bottom face of I-methylcycJopentene, it is equally likely to attack the top face, leading to the enantiomer. s=<:. BH3 · THF .. 8-13 (a) CH3 6 ,'QH 8-14 (a) (b) Et Et >=< Me H Z Et H >=< Me Et E (b) V major B H3 · THF B H3 • THF H + OH minor-steric hindrance to attack of BH 3 H S S Et � � Et K H ' M ' H " OH e ) enantiomers R S Et � � H K Me ' H
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