Solutions_Manual_for_Organic_Chemistry_6th_Ed 177

Solutions_Manual_for_Organic_Chemistry_6th_Ed 177 - 8 -31 0...

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8-31 R G ' C = O 0, t.H H 0 ± " ± " c t ) " " , / = C I trans H 8±32 All chiral products are racemIc m±xtures. R , c-o I I \ ² h ² R= < \- C³O i i M g 2 + o CH2cH3 (a) ± H (b) CH 3 CH2 oh ' HO / ch´CH 3 t H antI additION to a TR²S-alkenE G³ve´ HO H meso prodUct ² CH2CH 3 ² (cµ c µ¶·¸ Ch1 (dµ ± rotate tIsIstHe (e) ² h ·¸¹²S O OH ³ HO", C±S product ± H ¹± H ± H h »h 8-33 ´ H+ ² ¼ H ½ µ ± ³ 1 or ´ ch 0 H •• 3 H OCH 3 3 ¾o: ´ eºaºtIome»s H 8²34 All t¼ese ½eactions begiº wIth ac¼Iral reaGents; the½efore, all t¼e cHI»al products ¾»e »acem¿cÀ
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This note was uploaded on 02/27/2010 for the course CHEM 140 taught by Professor Wade during the Spring '10 term at Whitman.

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