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Solutions_Manual_for_Organic_Chemistry_6th_Ed 187

Solutions_Manual_for_Organic_Chemistry_6th_Ed 187 - in The...

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8-52 WithouT divinylbenzene, InDividual cHains of polystyrene are able to sLide past one another. Addition of divinYlbenzene duRng polymerizatIon fo±ms bridges, or "crossLinks², beTween chains³ addiNg sTrength and rigidiTY to the polyMer´ µivinyLbenzene and sim¶lar molecuLes are called crossLinKng agenTs· Two Po¸YstY±ene c¹ºins cross»in¼e½ by a divinYlbenzene monomer shown
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Unformatted text preview: in The dashed oval 8±²3 A peroxY rºdicaL is shown as The iniTiaTor¾ ¿eÀLY FoÁed bonds are shown in boLd H CH 3 \ / H C h \. ,C C I r "- v _ RO-C ± C² ³ i H CH 8³54 0, 'C´OCH2CH ± ethyl acrylate H2C=CH etc. -± 8´55 Ãn each caseÄ The compound (boxed) thaT produces the more stabLe carbocaTIoÅ is more reactÆve¾ (ºÇ (b) 0 3 " 6 a»LYlic (cÇ 180...
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