Solutions_Manual_for_Organic_Chemistry_6th_Ed 192

Solutions_Manual_for_Organic_Chemistry_6th_Ed 192 - 8-62...

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Unformatted text preview: 8-62 The two products from penaNgaNa¡e oxidatioN must Have beeN coNNected by a double boND at the carBoNYL carboNs. W¢e¡her t¢e alkeNe was E or Z caNNot be De¡eR Ned bY tHis experimeNt. C£3(C¤¥) 1¥C¦ = C£(C£¥§C¨© 8ª6« UNkNo¬­ X P¡ ®NkNo¬­ X Sho¬N here as Z whIch IS the NaturalLy¯occ°±I NG I²oMer ³°S¡ haVe ¡¢ree aLkeNeS IN ¡hIS SKeletoN o 0 CH2=O+Ho o 0 +Ah ´here are seVeraL ¬aYS ¡o a¡¡acK a proBleM LIKe ¡hISµ ONe IS ¡he ¡¶iaL¯aNd·e¸ror ¹ethoD, that ISº »°¡ ¼o°B½E BoNDs IN alL poSSIBle »oSI¡IoNS ¾N¡I l ¡¢e ozoNolYSIS pro¼¾cts ¹atch. ´here are tI¿es wHeN ¡he t¶ialÀaNd¯e±or Me¡¢od Ás uSeFÂL (aS I­ SI³pLe p¶oBleMS ¬here ¡he N°MBer oF possIBÁLItÁeS ÁS Few), But thi s is No¡ oNe oF ¡he³Ã Äe¡'s ¡ÅY loGIcµ ANalYze ¡he ozoNolYsIS »rod°c¡s careF°llYƬha¡ Do You see? THere are oNlY ¡¬o Me¡ÇÈl groupSº So oNe of the ¡¢ree ¡er¹ÉNal carÊoËs ÌË the SKeLe¡oN (C¯8, C¯9, or C· Í Î) has ¡o be a =C£¥ . Ïo groupSº So oNe of the ¡¢ree ¡er¹ÉNal carÊoËs ÌË the SKeLe¡oN (C¯8, C¯9, or C· Í Î) has ¡o be a =C£¥ ....
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