Solutions_Manual_for_Organic_Chemistry_6th_Ed 198

Solutions_Manual_for_Organic_Chemistry_6th_Ed 198 - CHAPER...

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Unformatted text preview: CHAPER 9-ALKYNES 9-1 Other structurEs are possible In each case. CH3CH2C:¡ CCH2CH3 CH3CH2CH2CH2C:¡ CH C¢£ CH HC¤¥ C ¦ CH2CH = C§CH2CH2¨H3 9©ª NEw «UA¬ ­®mES ®Re gIvEn¯ ThE ®stE°Sk ( * ) dEn±tes ®cEtyLEnIc hyd²±gEns of tE³m´­µ¶ ·LKY­¸¹º (®) (B» * CH3CH2 ¼C¤¥C ½ H B¾¿À Á ÀynE * CH3C§2C§2 ½ CÂÃC ½H PEntÀ Á ÀynE CH3 Ä C¤¥CÅC§3 B¾tƪÀynE CH3CH2 ½ CÇÈ C ÄCH3 PEn¿ÀªÉynE CH3 I * CH3CH Ä CÂÃC ½H ÊÉmEthylb¾tÉËÆynE ÌÍÎ ÏhE dEc±mP±SItI±n REacÐIon Bel±w Is Ex±thEÑIc ¡/0 = - ªÎ4 kJ/molE) ®S Well ®s h®vIng ®­ IncÒE®SÓ In EntÒ±PyÔ ÏhEÕmodyn®mÖc®lly, ®t 1500×CØ ®­ IncRE®sE In EntÕoPy WIll h®ve a large effect ±n AG (REmEmbeR aG = / ¢ TÙÚ)Û ÜnEtIc®llyÝ ®lm±st ®ny ®ctiva¿i±n EneRgy b®Þer Will be ovERc±mE at 1 500×Cß AcEtylEnE wo¾ld àikEày decomP±sE Int± its ElEmEntsá HCâCH 1 500× 2 C + H2 9À4 Adding s±dIum ®mÖdE t± thE mÖxt¾²E wIlL P²±ducE thE sodIum s®lt ±f heXÆÁ ÆynEã lE®vInG hExÆl ÍEnE...
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