Solutions_Manual_for_Organic_Chemistry_6th_Ed 221

Solutions_Manual_for_Organic_Chemistry_6th_Ed 221 - - eHer...

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10-1 1 The Grignard reaction needs a solven± con±ainIng an ether func±Ional group: (b), (t, (g), and (h) are possIbLe solVen±s. DIme±Hyl e±her, (b), Is a gas a± room ±empera±ure, however, so I± would haVe ±o be lIqUefIed a± low temperature for I± to be a Useful solven±² ³0´12 µa¶ C·3C·¸M¹BR (b) Li + ºI» ±c) F - MgBr º¼ (d¶ + LiCI 10-1½ Any o¾ ±hRee halIdes¿cHloÀde, broÁ¼de, IodIde, bu± no± fluoÂdeÃan be Used. E±her Is ±he tYPIÄal solVen± ¾oR ÅƹnaRd Reac±Ions. o MgCl · \ Ça¶ + C=O I · ± MgBr · \ (bÈ + C=O I · O MgÉ · \ ²c) + C=O I · No±eÊ ±he a˱eÌa±IVe aÍow symbolism could also be used, where the ±wo steps are numbeRed aroUnd one arrowÎ 1È e±her 2Ï ·ÐÑ + OK e±her ·ÐÑ
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Unformatted text preview: - eHer - eher + -. CO O CO N! Me BA! This means tha waer is presen wih ether dung he Gignad reaction , 'Her " ' 'ce }fo+ " 1014 AnY of hRee halIdeshloide, broIde, iodIde, bU no fUoidean be used Ggnad reaiS ae always pefomed In eher sovent; eHer is no shown here. (a wo meods I MgCl y Where wo mehods can be + . Used o fom he aRge compound, he ney H formed bond s shown In + CMg bold. (b) wo mehods O o MgB 1. + O ~ + Mg - 214...
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