Solutions_Manual_for_Organic_Chemistry_6th_Ed 238

Solutions_Manual_for_Organic_Chemistry_6th_Ed 238 - ºa...

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Note To The student: For simplIcIty, ±hIs book will use these standard LaboratoRy methods of OxIdatIon² -PCC (pyr³dinium chlorochromate) to oxidIze 1 ° aLcoHoLs to aLdehydes; ´µ2Cr04 (cHrom¶c acId) ±o oxidize 1 ° alcohoLs to carboxylIc acIds· ´¸r03, µ2S04¹ acetone ºJones reAgent» to oxiDIze aLcohoLs to Keto¼es. UnDe½¾¿and tha¿ othe½ choice¾ Àe LegItIMAteÁ for exAMpLe ÃWeÄ oxIdation worKs about as WELL PCC In tÅe prepaÆatIon of aldehydesÇ and ColLIns ½eAgent or PCC wILL oxIdize a aLcoÈoL to a ketone as welL as chroÉc AcidÊ Ëf you Have a question about the app½oprÌAteness of A reagent yOu cÈoOseÇ cOnsuLt the tabLe In the text befo½e ͽobLeM ±² -2. ±±³6 0
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Unformatted text preview: ºa» ε PÏC Ð • 0 ºbÑ OH µ2CÒ04 ± ÎÐ ± ² ¸r03 ³ ºc) ± µ2SÎ4 ε acetone 0 0 ºdÑ ÎÓ PCC ´ Ó ± 0 ± ÎÓ µ2Cr04 µ OH ºe» . (f oH µ2SÎ4 6 1 ) Bµ3• TH ( Ôµ Õr03 &0 ± ± • L 2) µÖ02× ÓÎØ µ2SÎ4 Ùµ2Î acetone ² ± ´7 Ú chronic alcoholIc has induced Mo½e ÚÛµ enzyÜe to be p½esent to handLe large amounts of iÜbÝÞeD ethAnoL, so requires more ethanol "antiDote" MoLecuLes to Act As A coÜpet³tive inhibitor to "tie upß the ext½A enZyme moLeculesà ² ² µ8 ε Îá [ 0 ] . Ô 0 I i ² ² Câ3ãCäCµ pyruvALDehyde ± ² ³ Ô 0 i i I i Cµ3åCæCÎÓ pyruvçc acId pyruvIc acid Is a nO½maL Me±abolite çn the b½eaèdown of gluco¾e º"blood sugé½ê) 231...
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This note was uploaded on 02/27/2010 for the course CHEM 140 taught by Professor Wade during the Spring '10 term at Whitman.

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