Solutions_Manual_for_Organic_Chemistry_6th_Ed 241

Solutions_Manual_for_Organic_Chemistry_6th_Ed 241 - 1 1 - 1...

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11-14 continued 2) Lucas test-istinguishes ± ° from alcohol by the rate of reaction R R + ZnCl2 + R OH + HCl . R Cl + H20 insoluble±" clouDy II In < I M²nUTe R R So³´bµe R R 2 ° R ± + . R ± + ·2O insoluble±"clouDy" ¸n ²³5 ¹ºn»te¼ H · so³´bµe H · R ² + . R ² + ·2O ¾nsoµUble¿ÀcloudyÀ ºn > 6 m¾n»tEs H H (no oBservable react¾Án at rÂÃÄ tE¹pÅ) soµ´ble --±±-²±±±-±--±±---±±±±±±±-±±±±±±±±±±±±±±±-±-±±³--±±-±±±±±±±±±±´±±-±-±-.±±±±±±±±±±±±´´_ µ¶ (a) (b) (c) (d) (e) ÆUcas: ·2Cr04: Lucas: HÇCÈ04: H2Cr04: LUcas: HÇCÉ04: ÊÇCË4Ì A cloUdy ¾n ±´5 m²nÍ ¾Îmediate bl´eÏgreen A c³oUdY ¾n ±-5 ÎinÐ ¾mÑed¾aÒe blUeÓgreen cloUÔÕ ºn ± ± ξnÖ no É×actiÃn¿stayS oÉange o no Éeaction no ÈeactionØstays orange cÙo»Ôy ¾n mÚnÍ ÛOÜÝ NOÞ ßàÝÞáNGâàݷغÄÄeÔ¾ate blUeãgreen for Both
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This note was uploaded on 02/27/2010 for the course CHEM 140 taught by Professor Wade during the Spring '10 term at Whitman.

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