Solutions_Manual_for_Organic_Chemistry_6th_Ed 242

Solutions_Manual_for - = a H a pproach C l from above H CH3 C CH3 This 3 ° c arbocation is planar at the C so that the C l can approach from the

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Unformatted text preview: = a H a pproach : C l : from above H CH3 C - CH3 + This 3 ° c arbocation is planar at the C+ so that the C l - can approach from the top or bottom gi ving b oth the cis and trans isomers. : Cl : approach from below = 0 C H3 ;: Cl CH 3 1 1-17 1 1-18 0 " , C H3 "H •• o� Z nCl2 • --- H 3 � OH + P BrJ -� 3 � G " � H3 + C 2° ·H - 3° h ydride shift O (from H CH I .� +C ' : Cl : " • • el) CH • O CI ' Br + P (OHh 1 1 - 19 ( a) 6 - OH S OCl2 CH3 ( b) 6 - OH 6 OT s Cl retention p yridine T sC I CH3 6 Cl N aCI S N2-inversion o A nother possible answer would be to use PCl 3 . 23 5 ...
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This note was uploaded on 02/27/2010 for the course CHEM 140 taught by Professor Wade during the Spring '10 term at Whitman.

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