Solutions_Manual_for_Organic_Chemistry_6th_Ed 244

Solutions_Manual_for_Organic_Chemistry_6th_Ed 244 - 1 1-2 1...

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Unformatted text preview: 1 1 -2 1 continued ( b) Cl IOH ZHnCI2 IClr B � HE r - PBr3 12 2 SOCl P - - I II I C I Cl (C) �OH ZHnCl2 �C � � �I 12 SOCI2 �C HBr � .. l Br Br PBr3 .. Br ( poor reaction on 3°) l P .. ( poor reaction on 3 °) - l (d) �OH ZHCl 2 nCI • no reaction unless heated, then S N I -rearrangement 1 °, n eopentyl HB r • P Br3 S OCIl. �Cl 2 37 � 12 � I P - S N2-minor (hindered) � Br + S N l -rearrangemen t � Br � CI (poor reaction on } O) Br ...
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This note was uploaded on 02/27/2010 for the course CHEM 140 taught by Professor Wade during the Spring '10 term at Whitman.

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