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Solutions_Manual_for_Organic_Chemistry_6th_Ed 255

Solutions_Manual_for_Organic_Chemistry_6th_Ed 255 -...

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1 1- 47 continued (b) PBr3 converts alcohols to bromides without rearrangement because no carbocation intermediate is produced. OH Br 11-48 PBr3 U · U H (a) U OH pec. o (b) V OH PBf3 V Bf (e) 0 0 H 0°- N a ' CH3 I . ( d) H OH q l H Q H q ' H SOCI2 OR CH3 CH3 CH3 retention H q l H TsC I ct- ..
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Unformatted text preview: pyÆdÇne ¿ÈÉ ¹µ3 ¹½3 Invers±on ·½ (e Ê ct µ2¿04 CK. ± I Y 1² 3 Ë 4 . ²³ Q ¶µ ÉÊ Me2¿ Oµ (f A ¹µ2 0µ µ2Àr04 Ì À··½ . ( g ² ² ¼ ¹r03 + 0 • Ã2¿O4 acetone (h) ³ 0µ µ2¿O4 ´ ´ ²i) I Ts¹Á µ ³ ´ Í Oµ P,Î2 . aI ´ pyÆdÏne Àµ3 Oµ Àµ3 ·Ts c²s cÐs 248...
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