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Solutions_Manual_for_Organic_Chemistry_6th_Ed 259

Solutions_Manual_for_Organic_Chemistry_6th_Ed 259 - a"f OH...

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1 1 -55 H Cl r ,., - oc/ :ci: 0 ( a ) ("f O H o H -z nCI 2 - �� V . . '- -- -A Z nCl2 V \ I n thi s presentat i on of the mec hanis m, th e HO Z- Cl } h + - n 2 Cl- + H20 t- ZnCI2 rearrangement i s sh own c onc urr ently wit ' . c leavage of th e C- O bond wi th no 1 0 H -Cl c arbocat i on i nter med i ate . ( b ) r'0 . r'0 �� � + - V O H H i" Q S 0 3 H V A .. _ V ; C ' H '- --'tf + 9 H H + H 2 0 H Onc e thi sc arboc at i on is formed, Cf( + H2 removal of adjac ent protons C __ -- --;
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