Solutions_Manual_for_Organic_Chemistry_6th_Ed 274

Solutions_Manual_for_Organic_Chemistry_6th_Ed 274 - 12 -2 1...

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Unformatted text preview: 12 -2 1 (a) D euter iU m h as twIc e th e mass of h ydr ogen, bU t s ImlA r s pr Ing c ons tant k . CompA r e Th e Fr equenc y oF C vIBr atIon to CH vIbr ation b y s ettIng U p a r atIo ch aN gIng only th e mass (sU Bs It te 2 m foR m) = = l = 0.707 Vo 07 07 vH 07 07 (3000 em-I) ' 2100 cm-1 () e Func tionaL gR oup mos t lIk eLy to e c onFus ed wIth a C D sR ec is te aLk yne (c aR on c aR o pE ond), wic appears In th e s ame r egion and is o ten ver y weak 1222 ( r- m /z 1 14 [+r mz 1 1 R* m /z 14 + m /z 5 1 + m /z 57 . m/z 5 a 1 c aR oc a ion no Favor aLe a 2 c aR oc a Ionr eas onaLe a 3 c aR oc ation e es e mos LiKeLy F R agmen ation oF 2 2 3,3 tetR ame yLu ane wiLL give a 3 c aR oc a ion h e mos t s aLe of t c ommon aLKyL c a ions e moLecU lar Io s ould Be s maLl or non exis tent wiLe m/z 57 is Lik eLy...
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