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Solutions_Manual_for_Organic_Chemistry_6th_Ed 287

Solutions_Manual_for_Organic_Chemistry_6th_Ed 287 - 1 3 1 8...

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1 3-1 8 continued (c) b H c H H b d H B r This compound has six types of protons. He and Hf are diastereotopic. a,b,c = & 7 . 2; d == & 5.0; e,f = & 3 .6 1 3 - 1 9 ( a ) .. � H a (d) H Cl \ / C=C / \ H H b c This compound has three types of protons. Ha and Hb are diastereotopic. a,b = & 5-6; c = & 7-8 H 1 CH CH -O-H 3 2 "" + H-B -- - + I') " . - CH3CH2 -�-H + .B -- - CH3CH2 - : + H-8 (b) . . ') " - CH CH -O-H +:B 3 2 .. � "" -- - CH3CH2 -R: + H-B H 1 -- - CH3CH2- O: + :B . . 13-20 The protons from the OH in ethanol exchange with the deuteriums in D2 0 . Thus, the
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