Solutions_Manual_for_Organic_Chemistry_6th_Ed 290

Solutions_Manual_for_Organic_Chemistry_6th_Ed 290 - 1 3-25...

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Unformatted text preview: 1 3 -25 Chemical shift values are estimates from Figure 1 3 -4 1 and from Appendix lC , except in (c) and (d), where the values are exac t. (a) estimated a a C�C l! 8 1 30 Q 8 70 b C I \ '0/ C b TMS 200 I 1 80 I 1 60 I 1 40 I 100 1 20 80 Carbon - 1 3 8 ( ppm) I I I 60 I 40 I 20 I I 0 I (b) estimated b a /C ' c C c i! c, / C aC c II I 8 1 25 Q 8 30 s;:. 8 22 b TMS 200 I 1 80 I 1 60 I 1 40 I 80 1 00 120 Carbon - 1 3 8 ( ppm) I I I 60 I 40 I 20 I I o I (c) exact values Q 8 1 45 s;:. 8 1 26 c CH2 d b,..-: ;' ' CH 3 a C /" C H3 e I 0 C g 8 26 � <5 1 7 l! 8 200 TMS 200 I 1 80 I 1 60 I 1 40 I 1 20 1 00 80 Carbon - 1 3 8 ( ppm) 2 83 I I I 60 I 40 I 20 I l o I ...
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