Solutions_Manual_for_Organic_Chemistry_6th_Ed 291

Solutions_Manual_for_Organic_Chemistry_6th_Ed 291 - 1 3-25...

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Unformatted text preview: 1 3-25 continued (d) exact values 12 8 1 36 f! � 8 1 35 H 8 1 92 /a \ C=C I c b\ H H II 0 C-H TMS 2 00 I 1 80 I 1 60 I 1 40 I 80 1 00 1 20 Carbon - 1 3 & (ppm) I I I 60 I 40 I 20 I I o I 1 3-26 (a) '68-- � t '637 0 '6209 (b) 30 -0- 2 = 1 5 37 -0- 2 . 7 = 14 8 -0- 1 = 8 -- 12 3H � 3H '630 A s a g eneral rule, the 1 5 -20 rule works fairly well. II b I I I I I I 0 2H TMS f! H3C-C-CH2-CH3 a I c I II 10 1 3-27 (a) 9 8 7 6 5 & (ppm) 4 3 2 I 1 I I I o / b C C=C a a f! \ '6 1 30 b '0/ C 12 '6 70 TMS 2 00 I 1 80 I 1 60 I 1 40 I 80 1 00 1 20 Carbon - 1 3 & ( ppm) 2 84 I I I 60 I 40 I 20 I 1 II1 o I ...
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