Solutions_Manual_for_Organic_Chemistry_6th_Ed 339

Solutions_Manual_for_Organic_Chemistry_6th_Ed 339 - 15-30...

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Unformatted text preview: 15-30 continued (e) (Note: Yield of the product in (f) would be small or zero due to severe steric interaction in the s -cis c onformation of the diene. See Figure 1 5- 1 6 . ) 15-3 1 (a) 0= I _ "" " , N ,e " " (f) eN ", ' ",CN ""'eN f 1 H2C �+ / � more significant contributor: 2 ° k 0( .. ( b) more significant contributor: 2 ° (c) ( d) i .. :0 0( H2 C == C - CH3 I : :0: (e) { { C H3-C=NH2 I - + :0: •• 0( .. C H3-C-NH2 II H �C � H H 0 H 0( .. t t more significant contributor-n egati ve charge on more electronegatIve atom more significant contributorn o charge separ ation 0 H H H � H2C H � H :0: . . :0: H .. .. H H H most sign i ficant contributorn egative c h arge on more electronegati ve atom 332 ...
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