Solutions_Manual_for_Organic_Chemistry_6th_Ed 340

Solutions_Manual_for_Organic_Chemistry_6th_Ed 340 - 15-31 c...

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Unformatted text preview: 15-31 c ontinued (f) m ost significant contributor---all atoms have ful l octets .. .. more significant contributor­ negative charge c an be stabilized b y electronegati ve ch lorines 15-32 ( a) The absorption at 1630 c m migration of the double bond_ (b) (c ) expected: UCH,CH,CH] OCH,CH2CH] d esired a ctual doubly allylic mlz 1 22 � . � .6 + - i s uggests a conj ugated alkene_ The higher temperature al lowed for actual : 15-33 (aj ( ( + [OCH,:f-CH2CH]] --{oCH, ml z 1 22 + mlz 79 � �H o ( b) 0 + ( dj + ¢ o o ( e) o + C'lL mlz 93 Cl CH2CH3 �CH' } � mass 43 +• mass 29 333 + ...
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