Solutions_Manual_for_Organic_Chemistry_6th_Ed 390

Solutions_Manual_for_Organic_Chemistry_6th_Ed 390 - 17-37...

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Unformatted text preview: 17-37 a) The kovori o i (Recal at radi al itia adds o an radical and l ori o a (Markovnicombinateintnatofon.HEr withl athfree-whatecverinspecitoesr generates tbromialnekene detesrmineseads etntantit oi­n.) The product wil tbee2-free-radical initiatporopane. de. bromo-l-phenyl r is a peroxi (b) Assume h R�R 'l RO· RO· r H r'Br ROH Br Br HCV HCH3 C: Br more stable than I first 6 � --- 2 + - --- + · . .. 6C I 2° (b) C( ) 2phenylpropane -bromo-l­ (Br ecycles chainrmechaniisnm) Br· Br MgBr 3 CH2CH20H a) HC=CH2 ( 3 CHCH H3 Mg H+ L\. --6� ether 6 Br OCH3 C�2CH3 CH3CH2Br CH30H hvor r2 9 AICl3 �OCH3 ortho BNBS OCH3 OCH3 OCH1 B' CN HN03 NaCN H2S04 BhvSor r2 Nrt02o NB N02 N02 oh • 17-38 + • 6 6ClI ¢ I , --­ • + 6C H3 ¢1I3 ¢]C I I I • ¢ + • ¢ 384 ¢ 1'1 • • ...
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This note was uploaded on 02/27/2010 for the course CHEM 140 taught by Professor Wade during the Spring '10 term at Whitman.

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