Solutions_Manual_for_Organic_Chemistry_6th_Ed 408

Solutions_Manual_for_Organic_Chemistry_6th_Ed 408 - Âs...

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18-6 AlL three target molEcules in this problem have MoRe than six carbons, so aLL answers wiLL inCLude caRbon-carbon±bond-fo²ing reactions. So faR, there aRe thRee types of Reactions that foRm carbon±c³RboN bonds: the G´ignard reactIonµ S¶2 substitution bY aN acetyL ide ion· and the F´iedeL¸¹Raºs Reactions (alkylation and acyLation) on benzene» 0 OH 0 (a) 0 B ¼ ± ½gB ¾ ¿)À ÀÁ¹ ; ± . etheR 2) À30 + (b) 0 U B ¼ ÂdenticaL sequeNce as Ân part (a) ~ I ± o 0 o ¹L ±² AL¹L3 ÄÅ U this Method UsiNÆ ÇÈedelɹRafts
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Unformatted text preview: Âs More efficÂenT as it Âs onLY oNe step (c) a synthesis as iN paRt (a) couLd aLso be used heRe Oà 0 ± Br Ëg ² ÌgBR 1± ± ³ L ´ l 2) H30 + . µ 6H Oà ¹ 4 ( BR Ía + ι=¹Ï ± ¹Ð¹À ² Àg Á + À 0 µ Á ³ HÁSOÑ O Ò8-7 (a) ( ³ BuÓi ´µ S X S S • • S : ¹ ' Ï À I Ï (b) ´ ¹Ï3Ô ³ S • • S S x S : C " . i ¹Ï3 Õ À Ö×oM (a² µ BR¹HÁ¹ÀÁPh ² S ¶ S Ph¹HÁ¹ÀÁ À BuÓi ¶· ´µ Ph Br ¶ 403 0 H30Ø ¸¸ ÄÅ Ph¹ÀÁ¹ÀÁ Ù¹À Àg¹ÚÁ ( Ph À30Û · Hg¹ÜÁ 0 Ýh ¸...
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