Solutions_Manual_for_Organic_Chemistry_6th_Ed 419

Solutions_Manual_for_Organic_Chemistry_6th_Ed 419 - 1 8-33...

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Unformatted text preview: 1 8-33 cont s (b) hydroliynsiuedmechanism continued OH OH order. pat th othbee ue because hi to fol t e id e energy e Thi h energypThihs,hasientcroscopirtreverse stepsbithave,sy processloiwsioanh8-equientil biricalum:minifimthumforward stpatpsh. fol loswis tmeinimum Princi le M c Reversi lit text sect n 4A. (d) of 6an-6ical, just�6 (c) The mechanisms of fonnation of an acetal and hydrolysis of acetal are ident the reverse ((·O � ·0· .. H +H + r +r H -O� .... OH :0, .... OH C C, � rOH ____ � H30+ HO I\ a famous CO-;;;o:CO 9 o RJ 0�+ H CJ:::'t /h·· + O� OH a () �+ OH '--- R 18-34 0 NaBH4 A CH30H V CHO 1 0 HO equivalent 1\ 1 equivalent OH ;-0- W .. 00-00 o� ·· � � CCl � CCl � '--•• • O +0 •• :0 I H H20: RH OH \� �� OH � tAhlidtseehydesoely,colsodiwilml itnrfastceterotxyborohydri).d(ekeepindg reactivi nare reduced icreasehseleketvones coul d u a an cti ity Al used for this reduction; see problem 18-13. be rnat CO . .: +O 1 H OH OH .. 414 ...
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This note was uploaded on 02/27/2010 for the course CHEM 140 taught by Professor Wade during the Spring '10 term at Whitman.

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