Solutions_Manual_for_Organic_Chemistry_6th_Ed 427

Solutions_Manual_for_Organic_Chemistry_6th_Ed 427 - 18-51 o...

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Unformatted text preview: 18-51 o OH OH (a) CH3-CH KCN.. CH3-CH-C::N H30+.. CH3-CH-COOH HCN 0= o HC ,Ph PhCH2Br Ph3P BuLi .. PhCH -PPh3 .. 6 00 NaBH4valent 00 1 equi (c) Al iv y, usin e tria o Problem .. selteectrnatelivyelreducesgthsodialudmehyde;cetseexyborohydride CH30H CHO CH20H uiv o o 1I10eq/\al0ent1! � NaBH4 H OH 30+. 11 (d) 0 � ,H CHPH" Q'"C'0 Q�1I0 C '0 C 0'" 0 CH3CH2CH2Br PPh3 t tBuLi quiv ent o o H1Oe/\alOH o CII3CH2CH -PPh� CHCH2CH3 30+ 5112:113 (e) 0 11 . .. H o,..C,0 C C '0 C 0'" o o o 1 equi2valent.. roo H ro Pt OHH o Raney .. ro H2 coOH (h) roo NaBH4 CII,oIl· roll II I I (b) + .. 18-13. ' LJ '--1 + + ,II LJ LJ II (g) f) ( Ni 422 ...
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