Solutions_Manual_for_Organic_Chemistry_6th_Ed 430

Solutions_Manual_for_Organic_Chemistry_6th_Ed 430 - 3doaNe...

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18-55 The key to this problem is understaNdiNg ±ha± ±he rela±ive proximItY of the two oxygeNs caN drama±icaLlY affec± their cHEmIstRy. ² ,2³d´ oxaNe Tµe "SecoNd" ´somer deSc¶Bed: two oXygens coNNec±·d BY a s´gma bond are a perox´de. The 0-0 BoNd is easiLY cLeaveD ±o g´ve rad¸ca¹S. ºN ±he preseNce of orgaN¸c coMpouNdS» rad´ca¹ reac±´ons ca¼ Be e½pLoS´ve¾ ¿ecHaNism of ace±aL HÀdrolÀsis HO O-H •• / Á :0 .²³´ fµ¶ · I + / C  Ã
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Unformatted text preview: 3doaNe Te "hrd" SoMer deScrBed Wo oxYgeNS BoNded to the saMe sp carBo coNsiue aN aceaL Which iS hYdroYzed N aqueouS acd ee he MecaSM BeoW 0 C CH + 0 " ' H } 425 ( ) o ,4dioxaNe hE first" isomer deScrbeD an excelLeN soLveN (aOUG oXic), these oYgeNS are far EnougH apa o ac iNdep deNtlY is a SMpe ee ( / H C ' '0 " ' H...
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This note was uploaded on 02/27/2010 for the course CHEM 140 taught by Professor Wade during the Spring '10 term at Whitman.

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