Solutions_Manual_for_Organic_Chemistry_6th_Ed 434

Solutions_Manual_for_Organic_Chemistry_6th_Ed 434 - 18-63...

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Unformatted text preview: 18-63 (a) � H (b) �CH2 (c) �C=CH 1) O ---.- PCC �H �H o o BuLi Cl o .. HgCl2 o (e) � Cl II ---.- (This reaction needs a solvent like THF to keep all reactants in solution.) 1) KOH H20 �H �H o (f) � 18-64 LiAIH4 OR � (a) � o OH H30+ ft OH (b) (e) 2) .. � PCC -- SOCl, " � Cl OH � (Ot-BuhH ft (c) o II �H o � o + � 0 + � 18-65 (a) ketone: no reaction (c) enol of an aldehyde-tautomerizes to aldehyde in base: pOSitive (d) hemiacetal of an aldehyde in equilibrium with the aldehyde in base: positive (e) acetal-stable in base: no reaction (f) hemiacetal of an aldehyde in equilibrium with the aldehyde in base: positive 429 (b) aldehyde: positive ...
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This note was uploaded on 02/27/2010 for the course CHEM 140 taught by Professor Wade during the Spring '10 term at Whitman.

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