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Solutions_Manual_for_Organic_Chemistry_6th_Ed 434

Solutions_Manual_for_Organic_Chemistry_6th_Ed 434 - 18-63(a...

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18-63 (a) O H (b) CH2 (c) C=CH PCC -- -.- o H o H o 1) BuLi .. HgCl2 �H Cl (e) Cl KOH ---.- H20 o H (This reaction needs a solvent like THF to keep all reactants in solution.) o II 1) LiAIH4 (f) OH .. o PCC II OH -- H 2) H30+ ft SOCl, ft ( O t -B uhH OR O H " Cl 18-64 (a) o 18-65 (a) ketone: no reaction (b) aldehyde: positive
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