Solutions_Manual_for_Organic_Chemistry_6th_Ed 452

Solutions_Manual_for_Organic_Chemistry_6th_Ed 452 -...

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Unformatted text preview: oxitmrnatiGsiveneralt,a catalUseciitel nNa(CH3COOhBH in solfortioreductivethamiimniatnieoor iuseinLiumliHon4 when tihseoliamteid.ne or e iseloly eguidy hydrogenatcieonofworks in mostncases. e n: m i A is not d. es for choi reagent u when Al e 0 (a) (i' H 0 -CH3 H2NOH PhCH2 NOH LiAlH4 PhCH2 -C -CH3 NH2 PhCH2 -C - C -CH3 H2O H (c) H CH2Ph 0 Na(CH3COOhBH 0 Ph)l H 0 N,Ph (d) 0 NHPh LiAlH4 H+ 6 6 H2O 6 NOH (e) 0 H2NOH LiAlH4 OR H2O 66 H 19-26 (b) II if .. II 1) 2) I .. I I I + .. + W 2) .. -. 1) 2) .. 1) 2) .. c5 1) 2) (a) H I 19-27 (b) 6 0 + + Cl � a 0 --- CI 'l) --- LiAlH4 r" 0 H20 0 0 HN� I)UAIH 6 HNJ) 6 H20 � :::::... .. 0-r cH� A A :::::... 2) 447 ...
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