Solutions_Manual_for_Organic_Chemistry_6th_Ed 454

Solutions_Manual_for_Organic_Chemistry_6th_Ed 454 -...

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Unformatted text preview: continued (e) Br\�H N aN H N3 LiAIH4 � 3� � � inversion Br\�H NaCN LiAIH4 �H2NH2 � inversion (g) 0 KCN HO CN CN � LiAIH4 H� �H used viTrtoualreducetenitroaromatyic. s,Assume a workup in base toplgiusvea tmetfreecatamiynste, fiornala metal pl.us HCI)can be ly in rchangeabl the reducing reagents (H2 he al al product (a) nCl H o Br Br Br (b) Fe HCI 6 o Nort0h2o n f; Br HCI )) Br U U from (a) COOH COOH (d) e Jr NO HFCI 6U CH30 y-:�H :0: �' 0 R-C- � : R-C=N,: R-C N) Br hCH T-C � H H H CH3 H ( HH , 19-30 R SN2- .. 1) • NH2 S (D R SN2- .. 1) .. S .. 1) .. 19-3 1 S • ¢¢ • + 2) S 19-32 P 2- , II - � , . �. ,"-, 2 .. II .. - ---- 449 mechan;,m cont;nued on next page : � :0: } , B, U II � .. ' ! ...
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This note was uploaded on 02/27/2010 for the course CHEM 140 taught by Professor Wade during the Spring '10 term at Whitman.

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