Solutions_Manual_for_Organic_Chemistry_6th_Ed 456

Solutions_Manual_for_Organic_Chemistry_6th_Ed 456 - 19-35...

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Unformatted text preview: 19-35 Please refeR to soLution ¡¢20, page ¡2 of this SoLutIoNs MaNuaL. ¡9-36 (a) pR£maRy amiNe; 2¤2¢dimethylpRopan¥¦§a¨©ne¤ or neopentylamªNe (b) secondaRy amªne; «¬methylpRopaN-2-a¨ªne¤ oR IsopRopYlmethy­amiNe (c) TE®¯a° HeTERoC±C­¯C am²³E a³D a ³£´µo GRoUp¶ ·¬N¯TRop±¸D¯NE (d) quate¹Ary heteRocyºliº am»onium ion; ¼½¼¾dimethYlpipeR¿d¿N¿um Iod¿de (e) teRt¿ary aromat¿º amªne oxide; ¼Àethyl¬¼-methylaN¿lINe oXIde (f) ÁeÂiary aromatiº amªneà ¼Äethyl¬¼-methy­an¿lIne (Å) teRt¿ary heteRocyclic am»onium £oN; pyÆidiniUm chloRide (h) seºondarY a¨ine; ¼¤4¬dIethylhexan¬3¬amine Ç9È37 Shown ¿N oRdeR of inºreasiNÅ basic¿tyÉ Ên sets a¬º¤ the al¿phaË¿º amÌne is Ëhe stRoNgest baseÍ Î I (a) PHÏ«ÏPh Î I « 0 < (b) pYÐoÑe (º) C«Ò < pyRRo­e < Óh«ÎÔ « 0 < H "« \ I < Ò < o ÕÎÔ aÑÖphatIc amine is the sËRonÅE×Ë ba×E aÑIphatÖc amªne ¿s the stRongest base; pyÆRole's aRomatiºItY wouLd...
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This note was uploaded on 02/27/2010 for the course CHEM 140 taught by Professor Wade during the Spring '10 term at Whitman.

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