Solutions_Manual_for_Organic_Chemistry_6th_Ed 457

Solutions_Manual_for_Organic_Chemistry_6th_Ed 457 - 2 for a...

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19-38 (a) not resolvable: planar (c) not resolvable: symmetric (e) not rEsolvabLe: syMmetRc (g) not resolvable in condiTions where the proton on N can exchange (b) resoLVab±e² asymmet³Ic carbon ±d) resoLVAbLe² NItrogen In´ersion is Veµy S±Ow (f resoLVabLe¶ asy·et³Ic nItrogen, uNab¸¹ to º»¼½rt (h) resoLVab±e¾ asyMmet³ic nitrogen¿ uNaBÀ¹ to ÁÂvEÃt ±9²³9 ²he values of pKÄ of amInes or pkÅ of the conjugate acids can Be ob³a´ned from µable ±9´³. THE side Æf th¹ reacTion wIth tÇe weaÈer acid anD base will be faVored at equI±IbRum. ÉÊee Ëppe»dix
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Unformatted text preview: 2 for a dscusson of acIdIty and basIcIty) ( a ) (b) I c ) H + D ) O N 3 i + pk 460 940 (a) PhC2C2 2 9-4 . -o H Q H I J + C3C-N + I H p 875 + C3C .N, H H pK " o N + p 2 2 n i + . + , p 27 products aRe FavORed reactants aRe FaVed pducts aRe FaveD pRoducts aRE FaR c( n reentioN f confIguratIon a) PhC2C2C22 b) 2 d-CJ d eN, o OH (e) N i 3 452 () 2 I afte wrup wIth base...
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