0243Pb68-2009

0243Pb68-2009 - 9 is racemic. Explain mechanistically. CH 2...

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Problem 68, Chemistry 0243 - 2009 Optically active 8 and optically active 9 react with thiolate ( SH) to give the corresponding mercaptans (RSH), but the product from trans compound 8 is still optically active, whereas the product from cis compound
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Unformatted text preview: 9 is racemic. Explain mechanistically. CH 2 OCH 3 CH 2 OTs SH CH 2 OCH 3 CH 2 OTs SH CH 2 OCH 3 CH 2 SH CH 2 OCH 3 CH 2 SH op. active still op. active racemic! op. active 8 9...
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This note was uploaded on 03/02/2010 for the course CHEM orgo taught by Professor Jones during the Fall '10 term at NYU.

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