Pb86-0243-09 - 3 COOOH and a single frog ’ s toe Be...

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Problem 86, Chemistry 0243 - 2009 Provide syntheses for the following products. You may start from methylenecyclohexane ( 1 ), inorganic reagents of your choice (no carbons) and sodium hydride (NaH), peroxides (ROOR), diazomethane (CH 2 N 2 ), tert -butyl alcohol [(CH 3 ) 3 COH], carbon tetrachloride (CCl 4 ), chloroform (CHCl 3 ), chlorophyll, Clorox (H 2 O/Cl 2 ), chlordane, chloramphetamines, dimethyl sulfide (CH 3 SCH 3 ), trifluoroperacetic acid (CF
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Unformatted text preview: 3 COOOH), and a single frog ’ s toe. Be careful how you write these answers. “A” means “Add clorox and a frog ’ s toe to X all at once .” “B” means, “First add clorox to X, then, in a second step , add a frog ’ s toe.” 1. clorox 2. frog's toe frog's toe clorox B X X A O OH OH OH Br O Br OH O ??? (a) (b) (c) (d) (g) (f) (e) (h) (i) (j) (k) 1...
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