0243Pb22an-09

0243Pb22an-09 - charges. ...... ) Step 2: make C—Cl only,...

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H 3 C H 3 C CH 3 CH 3 H—Cl H 3 C H 3 C CH 3 CH 3 H Cl H 3 C H 3 C CH 3 CH 3 Cl H Answers to Problem 22, Chemistry 0243 - 2009 Step 1: break π and H—Cl = 66 + 103 = 169 kcal/mol make C—H = ~ 96 So, this reaction is endothermic by at least 169 – 96 = 73 kcal/mol (and then there are those
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Unformatted text preview: charges. ...... ) Step 2: make C—Cl only, so this reaction is exothermic by about 85 kcal/mol (and those charges go away). What is the thermochemistry of the overall process?...
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This note was uploaded on 03/02/2010 for the course CHEM orgo taught by Professor Jones during the Fall '10 term at NYU.

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