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0243Pb30an-09 - large chloro group equatorial Ring...

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Answers to Problem 30, Chemistry 0243 - 2009 The more stable conformation of cis -1-chloro-3-fluorocyclohexane is the one with the two groups equatorial. Ring flip” generates the less stable conformation with the two alkyl groups axial. Each of these two diastereomers is chiral. Cl F H H Cl F H H Cl F H H Cl F H H cis -1-chloro-3-fluorocyclohexane more stable diastereomer These two forms are diastereomers. less stable diastereomer Neither mirror image is superimposable on the original - both diastereomers are chiral. flip The situation is the same in the trans molecule. The more stable conformation has the
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Unformatted text preview: large chloro group equatorial. Ring “flip” generates the less stable conformation with the large chloro group axial. Each of these two diastereomers is chiral. F H H Cl F H H F H H Cl F H H Cl trans-1-chloro-3-fluorocyclohexane less stable diastereomer These two forms are diastereomers. more stable diastereomer flip Neither mirror image is superimposable on the original - both diastereomers are chiral. Cl...
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