CHEM 482 problem set 3 UPDATED

CHEM 482 problem set 3 UPDATED - 3.2, 3.3, 3.6, 3.7, 3.8...

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Problem Set 3 (Updated 10/21/09) CHEM 482 Atomic Structure and Atomic Spectra Fall 2009 PART I: Suggested completion date: October 12, 2009 (This assignment will not be collected.) Read the following sections in Atkins: 2.6-2.7 3.1.0, 3.1(a), FI3.1 Solve the following in Atkins: Exercises: 2.16b Problems: 2.20 (evaluate expectation values where necessary), 2.23 3.15 PART II: Suggested completion date: October 26, 2009 (This assignment will not be collected.) Read the following sections in Atkins: 3.1-3.2 Solve the following in Atkins: Discussion Questions: 3.4 Exercises: 3.2b, 3.3b, 3.5b, 3.7b, 3.8b Problems: 3.12, 3.14, 3.17, 3.18, 3.19, 4.24
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PART III: Suggested completion date: November 9, 2009 (This assignment will not be collected.) Read the following sections in Atkins: 2.8 3.3-3.9 Solve the following in Atkins: Discussion Questions:
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Unformatted text preview: 3.2, 3.3, 3.6, 3.7, 3.8 Exercises: 3.10b, 3.12b, 3.14b, 3.15b, 3.16b, 3.17b, 3.18b, 3.19b Problems: 3.5 Supplemental Problems 3.1, 3.2, 3.3 Supplemental Problem 3.1 Write the Slater determinant for the ground-state configuration of Be. Supplemental Problem 3.2 Classify the following two-electron wavefunctions as symmetric, antisymmetric or neither, with respect to exchange of electrons 1 and 2. a. [1 ? (1)2 ? (2) + 2 ? (1)1 ? (2)][ (1) (2) (1) (2)] b. [1 ? (1)2 ? (2) + 2 ? (1)1 ? (2)][ (1) (2)] c. [1 ? (1)2 ? (2) 2 ? (1)1 ? (2)][ (1) (2) + (1) (2)] d. [1 ? (1)2 ? (2) 2 ? (1)1 ? (2)][ (1) (2) (1) (2)] Supplemental Problem 3.3 An excited state of a C atom has the configuration 1s 2 2s 2 2p 1 3p 1 . List the possible term symbols for this configuration....
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CHEM 482 problem set 3 UPDATED - 3.2, 3.3, 3.6, 3.7, 3.8...

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