BDE Table

BDE Table - 88 iPr-H 95 HO-Br 56 Allyl-H 86 tBu-H 93 Cl-Cl...

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Homolytic Bond Dissociation Enthalpies, kcal/mol Alkyl-H HX Primary CX Me-H 105 H-F 135 Et-F 107 Et-H 98 H-Cl 103 Et-Cl 80 i Pr-H 95 H-Br 87 Et-Br 68 t Bu-H 93 H-I 71 Et-I 53 H-OH 119 Et-OH 92 C-C H-NH 2 107 Et-NEt 2 77 Me-Me 90 H-H 104 Me-CN 122 Et-Me 86 H-CN 124 Et-Et 82 H-OAc 106 C-O t Bu- t Bu 72 H-OMe 104 Me-OH 92 Ac-Me 77 H-SH 91 Me-OMe 83 H-CF 3 106 CH 2 =O 175 Alkene/ Alkyne H-CCl 3 96 CH 2 =O, pi 90 H 2 C=CH 2 171 H-SPh 82 Thioketal C-S 65 H 2 C=CH 2 , pi 65 H-CH 2 CN 86 HC CH 230 H-CH(CH 3 )OR 92 Oxidants RCC-H 131 Me-H 105 HO-OH 51 RCH=CH-H 110 Et-H 98 tBuO-OtBu 38 H 2 C=CH-Cl
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Unformatted text preview: 88 iPr-H 95 HO-Br 56 Allyl-H 86 tBu-H 93 Cl-Cl 58 Allyl-Cl 69 PhO-H 86 Br-Br 46 RCC-H 131 I-I 36 Aryl RCH=CH-H 110 MeNH-NHMe 39 Ph-NH 2 102 Bn-H 88 MeS-SMe 60 Ph-CH 3 101 Ac-H 88 Ph-H 111 Cyclopropane-H 109 Silane/ Stannane Ph-F 126 Bu 3 Si-H 76 TMS-F 135 Ph-Cl 96 Bu 3 Sn-H 74 Bu 3 Si-H 76 Ph-Br 81 TMS-OH 108 Ph-I 65 TMS-CH 3 102 Bn-H 88 Bu 3 Sn-H 74...
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This note was uploaded on 03/04/2010 for the course CHEM 322AL at USC.

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